Published February 2005 | Version v1
Journal article Metadata-only

Nucleophilic cleavage of cyclic substituents in derivatives of the closo-decaborate anion

Creators

  • 1. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)

Description

A method was developed for synthesis of derivatives of closo-decaborate anion containing an alkoxy spacer between the functional groups and boron cluster. The structure of PbBipy(B10H9(OCH2CH2)2OEt)·0.5DMFA complex was established using data of IR spectroscopy, 11B NMR and X-ray diffraction analysis. The (2-B10H9(OCH2CH2)2OEt)- anion in the complex acts as a chelating ligand

Abstract (Russian)

Разработан метод синтеза производных клозо-декаборатного аниона с функциональными группами, отделенными от борного кластера алкоксильным спейсером. С использованием данных ИК спектроскопии, ЯМР 11B и рентгеноструктурного анализа установлено строение космплексного соединения PbBipy(B10H9(OCH2CH2)2OEt)·0.5ДМФА, в котором анион (2-B10H9(OCH2CH2)2OEt)- выступает в роли хелатирующего лиганда

Additional details

Additional titles

Original title (Russian)
Нуклеофильное раскрытие циклических заместителей в производных клозо-декаборатного аниона

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
50
Journal Issue
2
Journal Page Range
p. 243-249
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
38002018
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMIDES; BIPYRIDINES; BOND ANGLE; BOND LENGTHS; BOROHYDRIDES; BORON 11; CHEMICAL PREPARATION; ETHERS; INFRARED SPECTRA; LATTICE PARAMETERS; LEAD COMPLEXES; MOLECULAR STRUCTURE; NMR SPECTRA; ORGANIC PHOSPHORUS COMPOUNDS; TRICLINIC LATTICES
Descriptors DEC
AZINES; BORON COMPOUNDS; BORON ISOTOPES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIMENSIONS; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; ISOTOPES; LENGTH; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PYRIDINES; SPECTRA; STABLE ISOTOPES; SYNTHESIS

Optional Information

Notes
7 refs., 3 figs., 6 tabs.