Published May 1994 | Version v1
Journal article Metadata-only

129I Moessbauer spectroscopic study of metallocene-iodine adducts

Creators

  • 1. Dept. of Chemistry, Faculty of Science, Hiroshima Univ. (Japan)
  • 2. Dept. of Chemistry, Coll. of Arts and Sciences, Univ. of Tokyo (Japan)
  • 3. Research Reactor Inst., Kyoto Univ., Osaka (Japan)

Description

A 129I Moessbauer spectroscopic study of iodine adducts of ferrocenophane, biruthenocene, and osmocene is reported. The spectra show the existence of iodine bonded to the central metals of metallocenes in addition to triiodide anions. The valence state of iron in the ferrocenophane-iodine adduct is the same as those of ruthenium and osmium in their adducts. (orig.)

Additional details

Publishing Information

Journal Title
Hyperfine Interactions
Journal Volume
84
Journal Issue
1-4
Journal Page Range
p. 545-549.
ISSN
0304-3843
CODEN
HYINDN

Conference

Title
RIKEN international symposium on unstable nuclei and particles as probes in physics and chemistry (UN3PC92).
Dates
31 Aug - 2 Sep 1992.
Place
Wako (Japan).

INIS

Country of Publication
Netherlands
Country of Input or Organization
Switzerland
INIS RN
25076804
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
ABSORPTION SPECTRA; ADDUCTS; ELECTRONIC STRUCTURE; EXPERIMENTAL DATA; FERROCENE; IODINE 129; IRON IONS; MOESSBAUER EFFECT; MOLECULAR STRUCTURE; ORGANIC IODINE COMPOUNDS; ORGANOMETALLIC COMPOUNDS; OSMIUM COMPOUNDS; RUTHENIUM; RUTHENIUM COMPOUNDS; SPACE GROUPS; TEMPERATURE RANGE 0013-0065 K
Descriptors DEC
BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHARGED PARTICLES; COMPLEXES; DATA; DIENES; ELEMENTS; HYDROCARBONS; INFORMATION; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; IODINE ISOTOPES; IONS; IRON COMPLEXES; ISOTOPES; METALS; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PLATINUM METALS; POLYENES; RADIOISOTOPES; SPECTRA; SYMMETRY GROUPS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; YEARS LIVING RADIOISOTOPES