Published February 1976
| Version v1
Journal article
On labelled compounds. Pt. 23
Creators
- 1. Technische Univ. Clausthal, Clausthal-Zellerfeld (F.R. Germany). Organisch-Chemisches Inst.
Description
The kinetic of the chlorine exchange between (36Cl)antimony(III)-chloride and hexachloropropene is studied in homogenous methylene chloride solution for its dependence on time, (36Cl)SbCl3, C3Cl6, concentration and temperature. A mechanism is given with a transition state with 4 molecules of SbCl3 und 1 molecule of C3Cl6. (orig.)
Abstract (German)
Die Kinetik des Chloraustausches zwischen (36Cl) Antimon (III)-chlorid und Hexachlorpropen wird in homogener Methylenchloridloesung auf ihre Abhaengigkeit von der Zeit, den (36Cl)SbCl3 und C3Cl6 Konzentrationen und der Temperatur untersucht. Es wird ein Mechanismus mit einem Uebergangszustand angegeben, an dem 1 Molekuel Hexachlorpropen und 4 Molekuele Antimon (III)-chlorid beteiligt sind. (orig./AK)Additional details
Additional titles
- Subtitle (English)
- Kinetics of the chlorine exchange between antimony(III)-chloride and hexachloropropene
- Original title (German)
- Markierte Verbindungen. T. 23
- Original subtitle (German)
- Kinetik des Chloraustausches zwischen Antimon(III)-chlorid und Hexachlorpropen.
Identifiers
Publishing Information
- Journal Title
- Zeitschrift für Naturforschung B
- Journal Volume
- 31
- Journal Issue
- 2
- Series
- Z. Naturforsch., B.
- Journal Page Range
- 238-241
- ISSN
- 1865-7117
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 7259546
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Is Lead record
- Yes
- Descriptors DEI
- ALKENES; ANTIMONY CHLORIDES; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHLORINE 36; ISOTOPE EFFECTS; ISOTOPIC EXCHANGE; LABELLED COMPOUNDS; ORGANIC CHLORINE COMPOUNDS; RADIOACTIVITY; TIME DEPENDENCE
- Descriptors DEC
- ANTIMONY COMPOUNDS; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHLORIDES; CHLORINE COMPOUNDS; CHLORINE ISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIOACTIVE MATERIALS; RADIOISOTOPES; REACTION KINETICS; YEARS LIVING RADIOISOTOPES
Optional Information
- Notes
- 8 figs.; 2 tabs.; 16 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent