Published May 15, 2019 | Version v1
Journal article

Study of Cs extraction in an ionic liquid system using a common anion in both aqueous and ionic liquid phases

  • 1. Kyungpook National University, School of Architectural, Civil, Environmental, and Energy Engineering (Korea, Republic of)
  • 2. Kyungpook National University, Research Institute of Advanced Energy Technology (Korea, Republic of)

Description

The effect of Tf2N, as a common anion in aqueous and ionic liquid (IL) phases, on Cs extraction in the IL system was investigated using C2mimTf2N as an IL and DCH18C6 as an extractant. The "common anion (Tf2N) effect" operated via the movement of Cs+·Tf2N from the aqueous phase into the IL phase by extraction in the form of Cs+·extractant·Tf2N, without any traditional cation exchange. The extraction product was recovered as a precipitate using a small amount of IL, which facilitated precipitation via supersaturation.

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
320
Journal Issue
2
Journal Page Range
p. 329-336
ISSN
0236-5731
CODEN
JRNCDM

INIS

Country of Publication
Hungary
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54121705
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ANIONS; CESIUM IONS; CROWN ETHERS; EXTRACTION; ION EXCHANGE; LIQUID WASTES; MOLTEN SALTS; PRECIPITATION; SUPERSATURATION
Descriptors DEC
CHARGED PARTICLES; ETHERS; IONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SALTS; SATURATION; SEPARATION PROCESSES; WASTES

Optional Information

Copyright
Copyright (c) 2019 Akad#Latin Small Letter E With Acute#miai Kiad#Latin Small Letter O With Acute#, Budapest, Hungary