EPR study of Cr charge state changing according to dislocation tubes in ZnS crystals

Short-term high-temperature annealing of ZnS crystals in a zinc atmosphere is shown to cause rapid Zn diffusion through dislocation pipes along growth-dislocation lines. As a result, the impurity ions of divalent chromium localized in the Cottrell atmospheres outside the Rid cylinders become singly ionized. Plastic deformation of such ZnS crystals or the passing of an electric current through them under a voltage higher than a certain threshold value leads to a decrease in the number of univalent chromium ions. This decrease can be explained by an increase in the radius of the Rid cylinders as growth dislocations leave the Cottrell atmospheres and by an increase in the linear density of their electric charge