Published December 15, 1988 | Version v1
Journal article

Precise nonvariational calculations on the helium atom

  • 1. Code 4651, Naval Research Laboratory, Washington, D.C. 20375

Description

The Schroedinger equation is solved directly for the ground state and excited 2 1S state of the helium atom by using a rapidly convergent hyperspherical method which involves no adjustable parameters. The double and triple coalescence points are taken into account analytically. The center-of-mass motion is treated nonperturbatively, and the cases of infinite and finite nuclear masses are considered. The inclusion of 169 hyperspherical functions yields the precision of a few parts in 109 and 108 for the expectation value of the Hamiltonian operator and for all other expectation values, respectively, for the ground state, with only slightly less accuracy for the excited state

Additional details

Publishing Information

Journal Title
Physical Review, A
Journal Volume
38
Journal Issue
12
Series
Phys. Rev., A.
Journal Page Range
5995-5999
ISSN
0556-2791
CODEN
PLRAA