Published December 15, 1988
| Version v1
Journal article
Precise nonvariational calculations on the helium atom
Creators
- 1. Code 4651, Naval Research Laboratory, Washington, D.C. 20375
Description
The Schroedinger equation is solved directly for the ground state and excited 2 1S state of the helium atom by using a rapidly convergent hyperspherical method which involves no adjustable parameters. The double and triple coalescence points are taken into account analytically. The center-of-mass motion is treated nonperturbatively, and the cases of infinite and finite nuclear masses are considered. The inclusion of 169 hyperspherical functions yields the precision of a few parts in 109 and 108 for the expectation value of the Hamiltonian operator and for all other expectation values, respectively, for the ground state, with only slightly less accuracy for the excited state
Additional details
Publishing Information
- Journal Title
- Physical Review, A
- Journal Volume
- 38
- Journal Issue
- 12
- Series
- Phys. Rev., A.
- Journal Page Range
- 5995-5999
- ISSN
- 0556-2791
- CODEN
- PLRAA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 20024084
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ACCURACY; ANALYTICAL SOLUTION; ATOMS; ELECTRONIC STRUCTURE; EXCITED STATES; GROUND STATES; HELIUM; SCHROEDINGER EQUATION; THREE-BODY PROBLEM; WAVE FUNCTIONS
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; ELEMENTS; ENERGY LEVELS; EQUATIONS; FUNCTIONS; MANY-BODY PROBLEM; NONMETALS; PARTIAL DIFFERENTIAL EQUATIONS; RARE GASES; WAVE EQUATIONS