Published May 1985
| Version v1
Journal article
13C-labelled benzo[a]pyrene and derivatives. An efficient pathway of labelling the 1-, 2-, and 3-positions
Creators
- 1. New Mexico Univ., Albuquerque (USA). Dept. of Chemistry
Description
A ten step synthesis of benzo[a]pyrene-1-13C, -2-13C, or 3-13C from 2,3,7, 11b-tetrahydrobenz[d,e]anthracen-3(1H)-one is described in which the initial step involves the condensation of this ketone with the lithium enolate of ethyl acetate. This completes the authors' synthesis of the twelve 13C labelled benzo[a]pyrenes. (author)
Additional details
Publishing Information
- Journal Title
- J. Labelled Compd. Radiopharm.
- Journal Volume
- 22
- Journal Issue
- 5
- Series
- J. Labelled Compd. Radiopharm.
- Journal Page Range
- 475-485
- ISSN
- 0362-4803
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 16076905
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BENZOPYRENE; CARBON 13; CHEMICAL PREPARATION; LABELLED COMPOUNDS; LABELLING
- Descriptors DEC
- AROMATICS; CARBON ISOTOPES; CONDENSED AROMATICS; EVEN-ODD NUCLEI; HYDROCARBONS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; STABLE ISOTOPES; SYNTHESIS