Published December 4, 2009 | Version v1
Journal article

f↔f electric dipole transitions; old problems in a new light

  • 1. Department of Physics, Nicolaus Copernicus University, ul. Grudziadzka 5, 87-100 Torun (Poland)

Description

Very well known difficulties of the theoretical description of the f↔f electric dipole transitions of lanthanides are addressed in the old language of the standard Judd-Ofelt (J-O) theory, which has been widely applied for more than 45 years. New light is shed on a competitive physical mechanism of these transitions, which is presented to complement the existing J-O model. Possible new solutions are given for the old problems of the negative intensity parameters obtained from the adjusting procedure. An alternative scheme for the reproduction of the hypersensitive transitions is discussed and a theoretical description of highly forbidden transitions 0-0 and 0-1 observed for Eu3+ and Sm2+ ions is presented.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jallcom.2008.11.044

Additional details

Identifiers

DOI
10.1016/j.jallcom.2008.11.044;
PII
S0925-8388(08)02023-9;

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
488
Journal Issue
2
Journal Page Range
p. 586-590
ISSN
0925-8388
CODEN
JALCEU

Conference

Title
25. rare earth research conference
Acronym
RERC08
Dates
22-26 Jun 2008
Place
Tuscaloosa, AL (United States)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42042877
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
E1-TRANSITIONS; EUROPIUM IONS; FORBIDDEN TRANSITIONS; SAMARIUM IONS; SPECTRA; SPECTROSCOPY
Descriptors DEC
CHARGED PARTICLES; ENERGY-LEVEL TRANSITIONS; IONS; MULTIPOLE TRANSITIONS

Optional Information

Copyright
Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.