Published December 4, 2009
| Version v1
Journal article
f↔f electric dipole transitions; old problems in a new light
Creators
- 1. Department of Physics, Nicolaus Copernicus University, ul. Grudziadzka 5, 87-100 Torun (Poland)
Description
Very well known difficulties of the theoretical description of the f↔f electric dipole transitions of lanthanides are addressed in the old language of the standard Judd-Ofelt (J-O) theory, which has been widely applied for more than 45 years. New light is shed on a competitive physical mechanism of these transitions, which is presented to complement the existing J-O model. Possible new solutions are given for the old problems of the negative intensity parameters obtained from the adjusting procedure. An alternative scheme for the reproduction of the hypersensitive transitions is discussed and a theoretical description of highly forbidden transitions 0-0 and 0-1 observed for Eu3+ and Sm2+ ions is presented.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2008.11.044Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2008.11.044;
- PII
- S0925-8388(08)02023-9;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 488
- Journal Issue
- 2
- Journal Page Range
- p. 586-590
- ISSN
- 0925-8388
- CODEN
- JALCEU
Conference
- Title
- 25. rare earth research conference
- Acronym
- RERC08
- Dates
- 22-26 Jun 2008
- Place
- Tuscaloosa, AL (United States)
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 42042877
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- E1-TRANSITIONS; EUROPIUM IONS; FORBIDDEN TRANSITIONS; SAMARIUM IONS; SPECTRA; SPECTROSCOPY
- Descriptors DEC
- CHARGED PARTICLES; ENERGY-LEVEL TRANSITIONS; IONS; MULTIPOLE TRANSITIONS
Optional Information
- Copyright
- Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.