Published May 1996 | Version v1
Journal article Metadata-only

Oxidation of naphthalene, 2-methyl-naphthalene and alpha-napthol by cerium(4) in perchloric acid solutions

Creators

Description

In the two-phase system aqueous or aqueous-acetonitrile solution of perchloric acid-carbon tetrachloride or n-hexane cerium(4), perchlorate oxidates with high yields alpha-naphthol and naphtalene to 1.4-naphthoquinone, as well as 2-methylnaphthalene to 2-methyl- and 6-methyl-1.4-napgthoquinone. Consumption of cerium (4) perchlorate for oxidation of 1 mmol of alpha-naphthol amounts to approx. 4.5 mmol, for oxidation of 1 mmol naphthalene or 2-methylnaphthalene approx. 6.5-7.5 mmol. Refs. 18, tabs. 4

Additional details

Additional titles

Original title (Russian)
Okislenie naftalina, 2-metilnaftalina i al'fa-naftola tseriem(4) v rastvorakh khlornoj kisloty

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
66
Journal Issue
128
Journal Page Range
p. 847-853.
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
28000068
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETONITRILE; AQUEOUS SOLUTIONS; CARBON TETRACHLORIDE; CERIUM COMPOUNDS; CHEMICAL REACTION KINETICS; CONDENSED AROMATICS; NAPHTHALENE; NAPHTHOLS; OXIDATION; PERCHLORIC ACID
Descriptors DEC
AROMATICS; CHEMICAL REACTIONS; CHLORINATED ALIPHATIC HYDROCARBONS; CHLORINE COMPOUNDS; DISPERSIONS; HALOGEN COMPOUNDS; HALOGENATED ALIPHATIC HYDROCARBONS; HOMOGENEOUS MIXTURES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; MIXTURES; NITRILES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHENOLS; RARE EARTH COMPOUNDS; REACTION KINETICS; SOLUTIONS