Published June 9, 1976
| Version v1
Journal article
Effect of additives on the reaction of monomeric silicon difluoride with 1,3-butadiene
Description
Recoil 31Si atom reactions with PF3 resulted in the formation of both singlet and triplet 31SiF2 in the ratio of 1.0:3.3. Singlet 31SiF2 reacted with 1,3-butadiene to give difluorosilacyclopent-3-ene-31Si, but triplet 31SiF2 only gave this product in the presence of paramagnetic molecules such as NO, NO2, or O2
Additional details
Additional titles
- Augmented title (English)
- Formation of difluorosilacyclopent-3-ene-"3"1Si, effect of NO, NO_2, O_2, CO, N_2O, propene, and isobutene
Identifiers
- DOI
- 10.1021/ja00428a014;
Publishing Information
- Journal Title
- Journal of the American Chemical Society
- Journal Volume
- 98
- Journal Issue
- 12
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 3474-3477
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 8280748
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- BUTADIENE; BUTENES; CARBON MONOXIDE; CHEMICAL PROPERTIES; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CYCLOALKENES; HOT ATOM CHEMISTRY; NITROGEN OXIDES; OXYGEN; PROPYLENE; SILICON FLUORIDES; SILICON 31; TRIPLETS
- Descriptors DEC
- ALKENES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMISTRY; DIENES; ELEMENTS; EVEN-ODD NUCLEI; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HOURS LIVING RADIOISOTOPES; HYDROCARBONS; ISOTOPES; KINETICS; LIGHT NUCLEI; MULTIPLETS; NITROGEN COMPOUNDS; NONMETALS; NUCLEI; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; POLYENES; RADIOCHEMISTRY; RADIOISOTOPES; REACTION KINETICS; SILICON COMPOUNDS; SILICON ISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent