Radiation fabrication of hybrid activated carbon and functionalized terpolymer hydrogel for sorption of Eu(III) and Sm(III) ions

In this work, a hybrid composite of activated carbon (AC) functionalized with terpolymer hydrogel of polyvinyl alcohol/polyacrylamide/polyacrylic acid (PVA/PAAm/PAA) was prepared by $\gamma$-irradiation and used efficiently for sorption of Eu(III) and Sm(III) ions from aquatic solutions. Sewage sludge from the wastewater treatment plant was used to prepare AC, then activated by zinc chloride (ZnCl${}_2$) and thermal treatment at 550 °C. The modification of AC by functionalized terpolymer has successfully occurred mainly to limit its precipitation and to increase its adsorption capacity which allowed capable interaction with the metal ions. Different advanced techniques were used to investigate the structure and properties of (PVA/PAAm/PAA)/AC composite before and after the sorption process. Using 20 kGy is sufficient to get gel fraction of 87.5% and equilibrium swelling was 39.1 g/g. The (PVA/PAm/PAA)/AC composite hydrogel showed a pHpzc at pH ∼3. FTIR and EDS confirmed the successful integration of the functional groups and constituent elements of AC into terpolymer hydrogel components. XRD results confirmed the typical diffraction peaks of AC in the composite and the calculated average crystallite size was 167.4 nm. The SEM morphology of AC appeared as grains distributed well into the composite. The effect of synthesized AC, PVA/PAAm/PAA and (PVA/PAAm/PAA)/AC sorbents were tested to uptake of Eu(III) and Sm(III) ions. The highest uptake was noticed for (PVA/PAAm/PAA)/AC composite and it was selected for studying the parameters affecting the sorption process such as pH, shaking time, initial concentration, and adsorbent dosage. Results of the experimental data showed that Langmuir isotherm and Pseudo-second-order kinetic models fit well the sorption process of both Eu(III) and Sm(III) ions with maximum sorption capacities of 173.24 and 160.41 mg/g and uptake percentage of 82.3% and 83.4%, respectively at the optimum conditions of pH 4, 180 min, 100 mg/L metal concentration and 0.01 g adsorbent mass. The thermodynamic parameters indicated endothermic and spontaneous nature of the sorption process. Additionally, the as-prepared composite afford high selectivity and uptake capacity for Eu(III) and Sm(III) ions at pH 4 even in the presence of competing cations; Cd(II), Co(II), Sr(II) and Cs(I). The (PVA/PAAm/PAA)/AC composite was used efficiently as a unique and selective adsorbent for the sorption of Eu(III) and Sm(III) ions.