Published 1990 | Version v1
Journal article

Palladium-assisted (Z)-(E) isomerization of styrenes

  • 1. Western Australia Univ., Nedlands (Australia). Dept. of Chemistry
  • 2. Cape Town Univ. (South Africa). Dept. of Organic Chemistry

Description

It is shown that treatment of stereoisomeric mixtures of styrenes with a catalytic amount of bis(acetonitrile)dichloropalladium(II) achieves smooth stereoisomerization of the (Z)-isomers to the (E)-isomers

Additional details

Publishing Information

Journal Title
Australian Journal of Chemistry
Journal Volume
43
Journal Issue
4
Series
Aust. J. Chem.
Journal Page Range
777-781
ISSN
0004-9425
CODEN
AJCHA

INIS

Country of Publication
Australia
Country of Input or Organization
Australia
INIS RN
21070168
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ALKENES; CATALYSTS; EXPERIMENTAL DATA; ISOMERIZATION; LIGANDS; NMR SPECTRA; PALLADIUM COMPLEXES; STEREOCHEMISTRY; STYRENE
Descriptors DEC
AROMATICS; CHEMICAL REACTIONS; COMPLEXES; DATA; HYDROCARBONS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPLEXES