Published July 2005 | Version v1
Journal article Metadata-only

Ammine borane: synthesis and physicochemical characterization

Creators

  • 1. GNTs RF Gosudarstvennyj Nauchno-Issledovatel'skij Inst. Khimii i Tekhnologii Ehlementoorganicheskikh Soedinenij, Moscow (Russian Federation)
  • 2. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. Kurnakova, Moscow (Russian Federation)
  • 3. RAN, Inst. Fizicheskoj Khimii, Moscow (Russian Federation)

Description

Ammine borane samples were synthesized in two ways and purified to a high-purity grade through multiple recrystallization from isopropanol. New data were obtained on the fundamental properties of ammine borane, namely, its melting temperature, thermal and hydrolytic resistance, and solubility in various solvents. The liquid-solid equilibria of the ammine borane-water system were studied. The main stages of the thermal destruction of ammine borane were studied. The pyrolysis products were identified

Abstract (Russian)

Образцы амминборана синтезированы двумя способами и очищены до высокой степени чистоты путем многократной перекристаллизации из изопропилового спирта. Получены новые данные по его основным свойствам: температуре плавления, термической и гидролитической устойчивости, растворимости в различных растворителях. Исследована плавкость системы амминборан-вода. Изучены основные стадии термической деструкции амминборана и определен состав продуктов термолиза

Additional details

Additional titles

Original title (Russian)
Синтез и физико-химические свойства амминборана

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
50
Journal Issue
7
Journal Page Range
p. 1066-1071
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36106706
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; BORON HYDRIDES; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; MELTING POINTS; NITROGEN HYDRIDES; PHASE DIAGRAMS; PURIFICATION; PYROLYSIS; PYROLYSIS PRODUCTS; SOLUBILITY
Descriptors DEC
BORON COMPOUNDS; CHEMICAL REACTIONS; DECOMPOSITION; DIAGRAMS; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDRIDES; HYDROGEN COMPOUNDS; INFORMATION; KINETICS; MIXTURES; NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLUTIONS; SYNTHESIS; THERMOCHEMICAL PROCESSES; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE

Optional Information

Notes
14 refs., 5 figs., 1 tab.