Published April 23, 1987
| Version v1
Journal article
Matrix isolation study of the interaction between water and the aromatic π-electron system
Description
The interaction of water (H2O, D2O, HDO) with toluene, the xylenes, pseudocumene, mesitylene, pentamethylbenzene, and hexamethylbenzene in argon matrices has been studied with infrared spectroscopy. Interaction energy estimates are given. The shapes of the observed absorption bands suggest that water executes a complicated motion relative to the ring plane of the aromatic hydrocarbon. The infrared spectrum of the benzene-water complex has been recorded as a function of temperature in argon, krypton, and nitrogen matrices
Additional details
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 91
- Journal Issue
- 9
- Series
- J. Phys. Chem.
- Journal Page Range
- 2253-2258
- ISSN
- 0022-3654
- CODEN
- JPCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 18078758
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; ARGON; BENZENE; CHEMICAL REACTIONS; CUMENE; DEUTERIUM COMPOUNDS; ELECTRONIC STRUCTURE; EXPERIMENTAL DATA; HEAVY WATER; INFRARED SPECTRA; KRYPTON; MATRIX ISOLATION; MESITYLENE; NITROGEN; TEMPERATURE DEPENDENCE; TOLUENE; ULTRALOW TEMPERATURE; VIBRATIONAL STATES; WATER; XYLENES
- Descriptors DEC
- AROMATICS; DATA; ELEMENTS; ENERGY LEVELS; EXCITED STATES; HYDROCARBONS; HYDROGEN COMPOUNDS; INFORMATION; NONMETALS; NUMERICAL DATA; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; POLAR SOLVENTS; RARE GASES; SOLVENTS; SPECTRA; SPECTROSCOPY