Published January 22, 1990
| Version v1
Journal article
A new approach to the study of normalized appearance energy of hot atom reaction product in optical isomers of tris(acetylacetonato)ruthenium(III)
- 1. Tohoku Univ., Sendai (Japan). Dept. of Chemistry
Description
Appearence energy is originally the threshold energy at which recoil products begin to be observed. The 'normalized appearance energy' for isomerization in Ru(acac)3 was estimated to be 29 eV, and that for free atom (or ion) formation was calculated to be 34 eV. The 5 eV difference seems to indicate an energy interval in which isomerization effectively occurs in the recoil reaction. (author) 18 refs.; 2 figs.; 1 tab
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 144
- Journal Issue
- 2
- Series
- J. Radioanal. Nucl. Chem. ;Letters.
- Journal Page Range
- 89-96
- ISSN
- 0236-5731
- CODEN
- JRNCD
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 21074200
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ACETYLACETONE; ENERGY YIELD; EV RANGE 10-100; HOT ATOM CHEMISTRY; ISOMERIZATION; ISOMERS; RECOILS; RUTHENIUM COMPLEXES; RUTHENIUM 103; RUTHENIUM 97
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHELATING AGENTS; CHEMICAL REACTIONS; CHEMISTRY; COMPLEXES; DAYS LIVING RADIOISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; ENERGY RANGE; EV RANGE; EVEN-ODD NUCLEI; INTERMEDIATE MASS NUCLEI; ISOTOPES; KETONES; NUCLEI; ORGANIC COMPOUNDS; RADIOCHEMISTRY; RADIOISOTOPES; REAGENTS; RUTHENIUM ISOTOPES; TRANSITION ELEMENT COMPLEXES