A modification of the Dirac time-dependent perturbation theory
Creators
- 1. Indian Association for the Cultivation of Science, Jadavpur. Dept. of Physical Chemistry
Description
Within the framework of the method of variation of constants, time-dependent perturbation theory is presented in a form that naturally eliminates the undesirable 'secular' terms for a time-independent perturbation, permits an order-by-order calculation of the exact wavefunction for a 'resonant' harmonic perturbation and offers a simple route to establish the adiabatic hypothesis in quantum mechanics. The formulation rests on the introduction of a flexibility in the choice of the phase factors associated with the varying amplitudes, together with development of a perturbation procedure that closely resembles the Brillouin-Wigner formalism in the static case, and which exploits the flexibility of the phase factors at each order of the theory. (author)
Additional details
Publishing Information
- Journal Title
- Proc. R. Soc. (London), Ser. A
- Journal Volume
- 394
- Journal Issue
- 1807
- Series
- Proc. R. Soc. (London), Ser. A.
- Journal Page Range
- 345-361
- ISSN
- 0080-4630
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 16003680
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ADIABATIC PROCESSES; AMPLITUDES; DIRAC APPROXIMATION; PERTURBATION THEORY; QUANTUM MECHANICS; RESONANCE; SCHROEDINGER EQUATION; TIME DEPENDENCE; WAVE FUNCTIONS
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; EQUATIONS; FUNCTIONS; MECHANICS; PARTIAL DIFFERENTIAL EQUATIONS; WAVE EQUATIONS