Published August 8, 1984 | Version v1
Journal article

A modification of the Dirac time-dependent perturbation theory

  • 1. Indian Association for the Cultivation of Science, Jadavpur. Dept. of Physical Chemistry

Description

Within the framework of the method of variation of constants, time-dependent perturbation theory is presented in a form that naturally eliminates the undesirable 'secular' terms for a time-independent perturbation, permits an order-by-order calculation of the exact wavefunction for a 'resonant' harmonic perturbation and offers a simple route to establish the adiabatic hypothesis in quantum mechanics. The formulation rests on the introduction of a flexibility in the choice of the phase factors associated with the varying amplitudes, together with development of a perturbation procedure that closely resembles the Brillouin-Wigner formalism in the static case, and which exploits the flexibility of the phase factors at each order of the theory. (author)

Additional details

Publishing Information

Journal Title
Proc. R. Soc. (London), Ser. A
Journal Volume
394
Journal Issue
1807
Series
Proc. R. Soc. (London), Ser. A.
Journal Page Range
345-361
ISSN
0080-4630