Published March 1976
| Version v1
Journal article
Thermal decomposition of NbCl2(OCH3)3
Creators
- 1. National Inst. for Researches in Inorganic Materials, Sakura, Ibaraki (Japan)
Description
The thermal decomposition of NbCl2(OCH3)3 in an atmosphere of argon or oxygen was carried out and the overall reactions of them were described. The structures of the solids produced by the pyrolysis were examined. TT-Nb2O5 was one of the main solid products and it contains a small amount of chlorine atoms in place of oxygen atoms. Then, it is suggested that the so-called TT-modification might be composed of not only one structure, but of various structures represented by the equation, Nbsub(6n-2)Xsub(16n-6) (n=1, 2, 3, ...). (author)
Additional details
Identifiers
Publishing Information
- Journal Title
- Zeitschrift für anorganische und allgemeine Chemie
- Journal Volume
- 421
- Journal Issue
- 1
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 71-77
- ISSN
- 0044-2313
INIS
- Country of Publication
- German Democratic Republic
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 7272411
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ARGON; CHLORIDES; HIGH TEMPERATURE; INERT ATMOSPHERE; NIOBIUM COMPOUNDS; NIOBIUM OXIDES; ORGANOMETALLIC COMPOUNDS; OXYGEN; PYROLYSIS; STRUCTURAL CHEMICAL ANALYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COHERENT SCATTERING; CONTROLLED ATMOSPHERES; DECOMPOSITION; DIFFRACTION; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; NONMETALS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RARE GASES; SCATTERING; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent