Emission factors of environmentally persistent free radicals in PM2.5 from rural residential solid fuels combusted in a traditional stove

Highlights: • The EPFRs characteristics vary with PM_2.5 depending on solid fuel types. • The EF_EPFRs of crop residue, firewood and bitumite combustion are calculated. • EPFRs emissions relate to urbanization levels and resident lifestyles in different areas. • EPFRs are more stable in PM_2.5 with higher organic carbon content during photoaging. Emission factors (EFs) are crucial for establishing emission inventory and subsequent health risk assessment of pollutants. However, the EFs of environmentally persistent free radicals (EPFRs) in PM_2.5 have not been well investigated. We measured EPFRs in PM_2.5 from burning of different solid fuels in a traditional stove widely used in rural China and calculated the EFs of EPFRs (EF_EPFRs). The characteristics of EPFRs varied greatly with PM_2.5 depending on the feedstock, and the EF_EPFRs of crop residue, firewood and bitumite was 2.13 ± 1.04, 1.40 ± 0.76 and 1.08 ± 0.39 (10²⁰ spins·kg⁻¹), respectively. The estimated results of EPFRs emission associated with PM_2.5 showed that the crop residue was the main contributor to the top four provinces with high EPFRs emissions in China in 2010. A wide range (0.03–4.89 cig·person⁻¹·day⁻¹) of equivalent cigarette number converted by inhaling EPFRs in PM_2.5 was observed. Provinces with higher equivalent cigarette number were mainly agricultural provinces, because the rural residents tend to use readily available fuels. Additionally, EPFRs in collected PM_2.5 during 2 - month photoaging were more stable in particles with higher organic carbon contents. Our findings provided a new insight into the risk assessment of PM_2.5 from different sources by taking EPFRs into consideration.