Published September 1987
| Version v1
Journal article
Radiation cross-linking of fluoropolymers: Pt.2
Creators
- 1. Academia Sinica, Changchun, JL (China). Inst. of Applied Chemistry
Description
On the basis of the results of IR analysis, ESR, ESCA and chemical anlaysis, the mechanism of radiation crosslinking of fluoropolymer Fs-46 was suggested. The crosslinking point of Fs-46 is not on the side chain-CF3-group, as Bowers suggest with their theoretical analysis, it may carried out with recombination of two side chain radicals directly, crosslinking with H type, or recombination of side chain radicals and chain end radicals through branching and then crosslinking. It is crosslinking with T type or Y type. The later one is the probable mechanism
Additional details
Additional titles
- Subtitle (English)
- Mechanism of radiation cross-linking of flioropolymer Fs-46
Publishing Information
- Journal Title
- J. Radiat. Res. Radiat. Process.
- Journal Volume
- 5
- Journal Issue
- 1
- Series
- J. Radiat. Res. Radiat. Process.
- Journal Page Range
- 12-16
- ISSN
- 1000-3436
- CODEN
- FYYXE
INIS
- Country of Publication
- China
- Country of Input or Organization
- China
- INIS RN
- 19087281
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CROSS-LINKING; ELECTRON SPIN RESONANCE; INFRARED SPECTRA; ORGANIC FLUORINE COMPOUNDS; ORGANIC POLYMERS; PHOTOELECTRON SPECTROSCOPY
- Descriptors DEC
- CHEMICAL REACTIONS; ELECTRON SPECTROSCOPY; KINETICS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; POLYMERIZATION; POLYMERS; RADIATION EFFECTS; REACTION KINETICS; RESONANCE; SPECTRA; SPECTROSCOPY