Published July 2008 | Version v1
Journal article

Relative permittivity behavior and temperature changes in linoleic acid during the phase transition

  • 1. Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw (Poland)

Description

In our earlier works several fatty liquids (edible oils and unsaturated fatty acids) which exhibit existence of a new phase induced by high pressure were presented. Conclusion of those experiments is that C=C bonds existence in these liquids plays a dominant role in a new phase occurrence. Relative permittivity in pure acids investigated till now seems to behave in specific way. That is why we decided to investigate linoleic acid (C18H32O2) under high pressure. In our experiment such quantities as: electric capacity, pressure and temperature were recorded. The experimental setup gives us also a possibility to conduct optical investigations. We observed a transmitted and scattered beams of close infrared light (λ = 800nm) in directions 00 and 900 towards the incident beam. Due to the rapid grow of temperature and the rapid change of transmitted and scattered beams we may say that observed phenomenon is a first order phase transition and a proof for the significant change of liquid structure. This paper contains time dependencies of permittivity, temperature, transmitted and scattered light intensity and also permittivity vs. pressure changes during the phase transition in linoleic acid and first of all measured data analysis which lets us explain the transition reasons

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/121/14/142005

Additional details

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
121
Journal Issue
14
Journal Page Range
[4 p.]
ISSN
1742-6596

Conference

Title
Joint 21. AIRAPT and 45. EHPRG international conference on high pressure science and technology
Dates
17-21 Sep 2007
Place
Catania (Italy)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
40048953
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CAPACITANCE; CHEMICAL BONDS; DATA ANALYSIS; LINOLEIC ACID; LIQUIDS; OILS; OPACITY; PERMITTIVITY; PHASE TRANSFORMATIONS; PRESSURE DEPENDENCE; TIME DEPENDENCE
Descriptors DEC
CARBOXYLIC ACIDS; DIELECTRIC PROPERTIES; ELECTRICAL PROPERTIES; FLUIDS; MONOCARBOXYLIC ACIDS; OPTICAL PROPERTIES; ORGANIC ACIDS; ORGANIC COMPOUNDS; OTHER ORGANIC COMPOUNDS; PHYSICAL PROPERTIES