Published June 20, 1986
| Version v1
Journal article
Reaction of the metaphosphate ion with nucleophilic molecules
Creators
- 1. L. V. Pisarzhevskii Institute of Physical Chemistry, Kiev, USSR
Description
The electronic and three-dimensional structures of products of the reaction of the metaphosphate ion with a number of nucleophilic molecules: NH3, H2O, H2S, were investigated by semiempirical MNDO methods. It was found that as a result of addition of the nucleophilic molecules to the PO3- ion, thermodynamically stable adducts with a quasitetrahedral structure, capable of dissociating with the elimination of H+, are formed
Additional details
Publishing Information
- Journal Title
- J. Gen. Chem. USSR (Engl. Transl.)
- Journal Volume
- 56
- Journal Issue
- 1
- Series
- J. Gen. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 29-33
- ISSN
- 0022-1279
- CODEN
- JGCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19039615
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- AMMONIA; ATOMIC MODELS; BOND ANGLE; BOND LENGTHS; COMPLEXOMETRY; CONFIGURATION INTERACTION; EFFECTIVE CHARGE; ELECTRON CORRELATION; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; ENERGY SPECTRA; FORMATION HEAT; HYDROGEN SULFIDES; IONIZATION POTENTIAL; MOLECULAR ORBITAL METHOD; MOLECULAR STRUCTURE; PHOSPHATES; PHOSPHORUS COMPOUNDS; PHOSPHORYLATION; QUANTUM MECHANICS; WATER
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL REACTIONS; CORRELATIONS; ENTHALPY; HYDRIDES; HYDROGEN COMPOUNDS; MATHEMATICAL MODELS; MECHANICS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POLAR SOLVENTS; REACTION HEAT; SOLVENTS; SPECTRA; SULFIDES; SULFUR COMPOUNDS; THERMODYNAMIC PROPERTIES
Optional Information
- Notes
- Translated from Zh. Obshch. Khim.; 56: No. 1, 35-40(Jan 1986).