Published June 28, 2016 | Version v1
Journal article

The melting of stable glasses is governed by nucleation-and-growth dynamics

  • 1. Department of Physics, University of Bath, Bath BA2 7AY (United Kingdom)
  • 2. Laboratoire Charles Coulomb, UMR 5221 CNRS-Université de Montpellier, 34095 Montpellier (France)

Description

We discuss the microscopic mechanisms by which low-temperature amorphous states, such as ultrastable glasses, transform into equilibrium fluids, after a sudden temperature increase. Experiments suggest that this process is similar to the melting of crystals, thus differing from the behaviour found in ordinary glasses. We rationalize these observations using the physical idea that the transformation process takes place close to a "hidden" equilibrium first-order phase transition, which is observed in systems of coupled replicas. We illustrate our views using simulation results for a simple two-dimensional plaquette spin model, which is known to exhibit a range of glassy behaviour. Our results suggest that nucleation-and-growth dynamics, as found near ordinary first-order transitions, is also the correct theoretical framework to analyse the melting of ultrastable glasses. Our approach provides a unified understanding of multiple experimental observations, such as propagating melting fronts, large kinetic stability ratios, and "giant" dynamic length scales. We also provide a comprehensive discussion of available theoretical pictures proposed in the context of ultrastable glass melting.

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Chemical Physics
Journal Volume
144
Journal Issue
24
Journal Page Range
vp.
ISSN
0021-9606
CODEN
JCPSA6

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49022754
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMORPHOUS STATE; CRYSTAL GROWTH; GLASS; KINETICS; MELTING
Descriptors DEC
PHASE TRANSFORMATIONS

Optional Information

Notes
(c) 2016 Author(s)