Published March 1989 | Version v1
Journal article Metadata-only

Ruthenium(3) and rhodium(3) complexing with dithioacids in dimethylformmide

Creators

  • 1. Kazanskij Gosudarstvennyj Univ., Kazan (USSR)

Description

By the methods of potentiometry and spectrophotometry by composition and stability of ruthenium (3) and rhodium (3) chelates with diethyldithiocarbaminate (DEDTC), ethylxantogenate (EX) and diethyldithiophosphate (DEDTP) in dimethylformamide are determined. Metal concentration was 5x10-4 mol/l, for the ligands it varied within 1x10-4-2x10-3 M. It is shown that stability of the complexes of the composition 1:3 increase in the series Ru(dedtp)-3<Ru(EX)3<Ru(DEDTC)3

Additional details

Additional titles

Original title (Russian)
Комплекособразование рутения (3) и родия (3) с дитиокислотами в диметилформамиде

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
59
Journal Issue
3
Series
Zh. Obshch. Khim.
Journal Page Range
543-548
ISSN
0044-460X
CODEN
ZOKHA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20074925
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMIDES; CHELATES; CHEMICAL COMPOSITION; DEDTC; RUTHENIUM COMPLEXES; SOLUTIONS; STABILITY; THIOPHOSPHORIC ACID ESTERS
Descriptors DEC
CARBAMATES; CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; CHELATING AGENTS; COMPLEXES; DISPERSIONS; ESTERS; HOMOGENEOUS MIXTURES; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; TRANSITION ELEMENT COMPLEXES