Published 1986 | Version v1
Journal article Metadata-only

Crystal structure of hemihydrate of aminoguanidonium hexafluorozirconate

Creators

  • 1. AN SSSR, Vladivostok. Inst. Khimii

Description

X-ray diffraction investigation of (CN4H8) ZrF6x0.5H2O is carried out. Crystals are monoclinic: a=6.847(1), b=28.282(2), c=8.236(1)A, γ=103.66(2)deg, ho=2.50 g/cm3, Z=8, sp.gr. P21/b. The (CN4H8)ZrF6x0.5H2O structure is formed of four-dimensional [ZrF7-ZrF8-ZrF8-ZrF7] complexes, aminoguanidonium groups ad water molecules. The coordination Zr polyhedrons are presented as slightly distorted polyhedrons: [ZrF8] prism. All vertexes of which are occupied by fluorine atoms. The compound structure and the system of hydrogen bonds in it are discussed

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура полугидрата гексафтороцирконата аминогуанидония

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
12
Journal Issue
5
Series
Koord. Khim.
Journal Page Range
710-714
ISSN
0132-344X
CODEN
KOKHD

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
18004960
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; CHEMICAL BONDS; FLUORIDES; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCLINIC LATTICES; ORGANIC NITROGEN COMPOUNDS; SPACE GROUPS; ZIRCONIUM COMPLEXES
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES