Improve photocurrent quantum efficiency of carbon nanotube by chemical treatment

Highlights: ► The QE of photocurrent for the H2O2-treated CNTs reaches to 5.28% at Ubias = 0.1 V. ► Moderate chemical treatment can enhance the QE of photocurrent of CNTs. ► Excessive chemical treatment decreases the photocurrent quantum efficiency of CNTs. - Abstract: High photocurrent quantum efficiency (QE) of carbon nanotubes (CNTs) is important to their photovoltaic applications. The ability of photocurrent generation of CNTs depends on their band structure and surface state. For given CNTs, it is possible to improve the QE of photocurrent by chemical modification. Here, we study the effects of simple chemical treatment on the QE of CNTs by measuring the photocurrent of macroscopic CNT bundles. The QE of the H2O2-treated CNT bundle reaches 5.28% at 0.1 V bias voltage at a laser (λ = 473 nm) illumination, which is 85% higher than that of the pristine sample. But the QE of the CNTs treated in concentrated HNO3 is lower than that of the pristine sample. It shows that moderate chemical treatment can enhance the photocurrent QE and excessive chemical treatment will decrease the QE because of introducing lots of structural defects.