Published February 1978
| Version v1
Journal article
Nonlinear determination of complexing constants in aqueous solutions by the least square method
- 1. Moskovskij Gosudarstvennyj Univ. (USSR)
Description
A program for nonlinear determination of complexing constants by the least square method from the data of pH-metric titration was compiled. To minimize the target function, the deformed polyhedron method Was used, whose choice is due to the fact that it has a number of advantages over the methods requiring calculation of partial derivatives. The program compiled was used for simulating equilibria and estimating their constants in the NaCl3 system hydrazinediacetic acid
Additional details
Additional titles
- Original title (Russian)
- Нелинейное определение констант комплексообразования в водных растворах методом наименьших квадратов
Publishing Information
- Journal Title
- Zh. Fiz. Khim.
- Journal Volume
- 52
- Journal Issue
- 2
- Series
- Zh. Fiz. Khim.
- Journal Page Range
- 385-388
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9413777
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S99: GENERAL AND MISCELLANEOUS;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARBOXYLIC ACIDS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; COMPLEXES; LEAST SQUARE FIT; NEODYMIUM CHLORIDES; ORGANIC NITROGEN COMPOUNDS; PH VALUE; PROGRAMMING; SIMULATION; TITRATION
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; KINETICS; MAXIMUM-LIKELIHOOD FIT; MIXTURES; NEODYMIUM COMPOUNDS; NUMERICAL SOLUTION; ORGANIC ACIDS; ORGANIC COMPOUNDS; RARE EARTH COMPOUNDS; REACTION KINETICS; SOLUTIONS; SYNTHESIS
Optional Information
- Notes
- For English translation see the journal Russ. J. Phys. Chem.