Published September 1, 2007 | Version v1
Journal article

The influence of precursor powder on the microstructure and properties of Bi-2212 blocks

  • 1. CEPEL - Electric Power Research Center, P.O. Box 68007, 21944-970 Rio de Janeiro, RJ (Brazil)
  • 2. PUC-Rio - Pontifical Catholic University, Department of Materials Science and Metallurgy, P.O. Box 38008, 22453-900 Rio de Janeiro, RJ (Brazil)

Description

The present work reports our investigations on the partial melt processing of bulk Bi-2212. Commercial and homemade precursor powders with different nominal compositions were melt-processed into silver molds. Samples were analyzed by XRD, SEM/EDS and DC critical current measurements. The main secondary phases forming upon Bi-2212 peritectic decomposition were 14:24 and 91150, besides 2201, which crystallizes from the liquid. The superconducting properties depended mainly on the precursor and on the maximum processing temperature. The commercial precursors provided the best results. Bi-2212 blocks with Ic = 90-135 A and Jc = 900-1350 A/cm2, at 77 K, have been obtained. However, reducing the amount of coarse secondary phases and optimizing the 2212 oxygen content may enhance the performance of bulk Bi-2212

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physc.2007.04.022

Additional details

Identifiers

DOI
10.1016/j.physc.2007.04.022;
PII
S0921-4534(07)00552-7;

Publishing Information

Journal Title
Physica. C, Superconductivity
Journal Volume
460-462
Journal Page Range
p. 1349-1350
ISSN
0921-4534
CODEN
PHYCE6

Conference

Title
8. international conference on materials and mechanisms of superconductivity and high temperature superconductors
Acronym
M2S-HTSC VIII
Dates
9-14 Jul 2006
Place
Dresden (Germany)

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.