Detection of Ionized Calcium in the Atmosphere of the Ultra-hot Jupiter WASP-76b

Recent observations of the ultra-hot Jupiter WASP-76b have revealed a diversity of atmospheric species. Here we present new high-resolution transit spectroscopy of WASP-76b with GRACES at the Gemini North Observatory, serving as a baseline for the Large and Long Program "Exploring the Diversity of Exoplanet Atmospheres at High Spectral Resolution" (Exoplanets with Gemini Spectroscopy, or ExoGemS for short). With a broad spectral range of 400–1050 nm, these observations allow us to search for a suite of atomic species. We recover absorption features due to neutral sodium (Na i), and report a new detection of the ionized calcium (Ca ii) triplet at ∼850 nm in the atmosphere of WASP-76b, complementing a previous detection of the Ca ii H and K lines. The triplet has line depths of 0.295% ± 0.034% at ∼849.2 nm, 0.574% ± 0.041% at ∼854.2 nm, and 0.454% ± 0.024% at ∼866.2 nm, corresponding to effective radii close to (but within) the planet's Roche radius. These measured line depths are significantly larger than those predicted by model LTE and NLTE spectra obtained on the basis of a pressure–temperature profile computed assuming radiative equilibrium. The discrepancy suggests that the layers probed by our observations are either significantly hotter than predicted by radiative equilibrium and/or in a hydrodynamic state. Our results shed light on the exotic atmosphere of this ultra-hot world, and will inform future analyses from the ExoGemS survey.