Published November 1980 | Version v1
Journal article

Spectroscopic investigations in the solid state chemistry. Pt. 13

Creators

  • 1. Technische Univ. Muenchen (Germany, F.R.). Anorganisch-Chemisches Inst.

Description

The temperature dependence of the electric field gradients was measured by I. and II. order quadrupole effects of the 127I NMR signals in scheelite-structured NH4IO4 and RbIO4, in pseudo-scheelite CsIO4 and in N(CH3)4IO4, where rsub(cation) > rsub(anion). An interpretation of the anomalous positive temperature dependences of the quadrupole coupling constants in NH4IO4 and in the isostructural NH4ReO4 is proposed. (orig.)

Additional details

Additional titles

Subtitle (English)
Temperature dependence of the "1"2"7I-nuclear quadrupole coupling in NH_4IO_4 and other periodates
Original title (German)
Spektroskopische Untersuchungen in der Festkoerperchemie. Pt. 13
Original subtitle (German)
Temperaturabhaengigkeit der "1"2"7I-Kernquadrupolkopplung in NH_4IO_4 und anderen Periodaten.

Publishing Information

Journal Title
Z. Naturforsch., B
Journal Volume
35
Journal Issue
11
Series
Z. Naturforsch., B.
Journal Page Range
1349-1354
ISSN
0044-3174