Published November 1982
| Version v1
Journal article
Perfluoroalkyl tellurium compounds: oxidation of (CF3)2Te; preparations and properties of (CF3)2TeCl2, (CF3)2TeBr2, (CF3)2Te(ONO2)2, and (CF3)2TeO
Creators
- 1. Dortmund Univ. (Germany, F.R.). Lehrstuehle fuer Anorganische Chemie
Description
From the oxidation of (CF3)2Te with Cl2, Br2, O2, and ClONO2 the new trifluoromethyl tellurium compounds (CF3)2TeCl2, (CF3)2TeBr2, (CF3)2TeO, and (CF3)2Te(ONO2)2 are prepared. The 19F, 13C and 125Te n.m.r. spectra, the vibrational and mass spectra as well as the chamical properties of these compounds are described. By variation of the reaction conditions CF3TeCl3 and CF3TeBr3 are also formed. It has not been possible to isolate (CF3)TeI2, but there is some evidence that it is formed as an intermediate. (CF3)2Te reacts with ozone to a very unstable compound, which decomposes at low temperature. (author)
Additional details
Additional titles
- Original title (German)
- Perfluoralkyltellur-Verbindungen: Oxidation von (CF
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 494
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 151-158
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 14749161
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CHEMICAL PROPERTIES; CHEMICAL SHIFT; FLUOROFORM; INFRARED SPECTRA; MASS SPECTRA; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLIC COMPOUNDS; RAMAN SPECTRA; TELLURIUM BROMIDES; TELLURIUM CHLORIDES; TELLURIUM NITRATES; TELLURIUM OXIDES
- Descriptors DEC
- BROMIDES; BROMINE COMPOUNDS; CHALCOGENIDES; CHLORIDES; CHLORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; MAGNETIC RESONANCE; NITRATES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RESONANCE; SPECTRA; SYNTHESIS; TELLURIUM COMPOUNDS