Published February 1, 1977 | Version v1
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Using the Wolfsberg--Schactschneider program to calculate equilibrium constants for isotopic acetylenes

Creators

Description

Equilibrium constants were calculated for the gas-phase isotopic exchange reactions C2H2 + C2D2 = 2C2 HD and C2H2 + D2O = C2D2 + H2O at temperatures ranging from 40 to 20000K. No corrections to the harmonic approximation were made. The results agree quite well with experimental measurements

Availability note (English)

MF available from INIS under the Report Number; Available from NTIS. $3.50.

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Additional details

Additional titles

Augmented title (English)
C_2H_2 + C_2D_2 #-># 2C_2HD; C_2H_2 + D_2O #-># C_2D_2 + H_2O; 40 to 2,000"0K

Publishing Information

Imprint Pagination
14 p.
Report number
UCRL--52210

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
8324013
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETYLENE; CHEMICAL REACTION KINETICS; DEUTERIUM; DEUTERIUM COMPOUNDS; EQUILIBRIUM; HEAVY WATER; HIGH TEMPERATURE; ISOTOPIC EXCHANGE; LOW TEMPERATURE; MEDIUM TEMPERATURE; TEMPERATURE DEPENDENCE; VERY HIGH TEMPERATURE; VERY LOW TEMPERATURE; VIBRATIONAL STATES
Descriptors DEC
ALKYNES; ENERGY LEVELS; EXCITED STATES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; STABLE ISOTOPES; WATER