Published June 2018 | Version v1
Journal article Metadata-only

Irreversible replacement of sodium with thallium in sodium coordination polymer nanostructures by solid-state mechanochemical cation exchange process

Creators

  • 1. University of Tehran, School of Chemistry, College of Science (Iran, Islamic Republic of)
  • 2. Ilam University, Departement of Chemistry, Faculty of Science (Iran, Islamic Republic of)
  • 3. Prince of Songkla University, Department of Materials Science and Technology, Faculty of Science (Thailand)

Description

Solid-state conversion of NaI coordination polymer nanostructure, synthesized by sonochemical procedure, to TlI coordination polymer has been observed upon liquid-assisted mechanochemical reaction of [Na2TP]n (1) (H2TP = terephthalic acid), with TlNO3. During this conversion, ion exchange process of Na(I) with Tl(I) was occurred and [Tl2TP]n (2) was synthesized. The X-ray diffraction (XRD) pattern of 2 after mechanochemical reaction of it with NaNO3 indicated that this transformation is irreversible. Compounds 1 and 2 were characterized by IR spectroscopy, X-ray powder diffraction (XRD), elemental analysis, thermogravimetric and differential thermal analyses and scanning electron microscopy.

Additional details

Identifiers

DOI
10.1007/s13738-018-1331-1;

Publishing Information

Journal Title
Journal of the Iranian Chemical Society (Print)
Journal Volume
15
Journal Issue
6
Journal Page Range
p. 1327-1335
ISSN
1735-207X
CODEN
JICSCJ

INIS

Country of Publication
Iran, Islamic Republic of
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
50030719
Subject category
S77: NANOSCIENCE AND NANOTECHNOLOGY;
Descriptors DEI
DIFFERENTIAL THERMAL ANALYSIS; INFRARED SPECTRA; ION EXCHANGE; NANOSTRUCTURES; POLYMERS; SCANNING ELECTRON MICROSCOPY; SODIUM; SODIUM NITRATES; TEREPHTHALIC ACID; THALLIUM; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION
Descriptors DEC
ALKALI METAL COMPOUNDS; ALKALI METALS; CARBOXYLIC ACIDS; CHEMICAL ANALYSIS; COHERENT SCATTERING; DICARBOXYLIC ACIDS; DIFFRACTION; ELECTRON MICROSCOPY; ELEMENTS; GRAVIMETRIC ANALYSIS; METALS; MICROSCOPY; NITRATES; NITROGEN COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SODIUM COMPOUNDS; SPECTRA; THERMAL ANALYSIS

Optional Information

Copyright
Copyright (c) 2018 Iranian Chemical Society