Published May 1978
| Version v1
Journal article
Some regularities of fragmentation of α-diol radicals
- 1. Belorusskij Gosudarstvennyj Univ., Minsk
Description
Studied are the specific features of fragmentation of the radicals of 1.2-propanediol, 2.3-butanediol, 1.2-dimethoxyethane, and some 1.3-dioxolanes generated by γ irradiation of diluted aqueous solutions. As a source of γ radiation 137Cs has been used; the absorbed dose rate is 4.1015 eV/(mlxs); the range of the doses used is 1.5x1019-1.5x1020 eV/ml. The method of gas-liquid chromatography has been used for studying the composition of the radiolysis products. The possibility of fragmentation of the radicals by the coordinated mechanism is shown
Additional details
Additional titles
- Original title (Russian)
- Некоторые закономерности фрагментации радикалов α-диолов
Publishing Information
- Journal Title
- Zh. Org. Khim.
- Journal Volume
- 14
- Journal Issue
- 5
- Series
- Zh. Org. Khim.
- Journal Page Range
- 920-923
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 10429586
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; DOSE RATES; GAMMA RADIATION; GAS CHROMATOGRAPHY; GLYCOLS; RADICALS; RADIOLYSIS
- Descriptors DEC
- ALCOHOLS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHROMATOGRAPHY; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; IONIZING RADIATIONS; KINETICS; MIXTURES; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SEPARATION PROCESSES; SOLUTIONS
Optional Information
- Notes
- For English translation see the journal J. Org. Chem. USSR.