Published January 1985
| Version v1
Journal article
Silylated azanides of Ti(IV) and Zr(IV)
Creators
- 1. Panjab Univ., Chandigarh (India). Dept. of Chemistry
Description
A convenient method is reported for the preparation of titanazanes, 1:1 and 1:2 reactions of TiCl4 with NaN(SiMe3)2 in tetrahydrofuran-hexane medium. An equimolar reaction of ZrCl4 with NaN(SiMe3)2 leads to bis(silyl)amide Cl3Zr-N(SiMe3)2, whereas reactions in higher molar ratios (1:2 and 1:4) lead to heterocycles, Cl2Zr-CH2-SiMe2-NSiMe3 and Zr(-CH2-SiMe2-NSiMe3)2, respectively. The compounds have been characterised by elemental analyses, molar conductance, infrared and 'H NMR measurements. (author)
Additional details
Publishing Information
- Journal Title
- Indian J. Chem., Sect. A
- Journal Volume
- 24
- Journal Issue
- 1
- Series
- Indian J. Chem., Sect. A.
- Journal Page Range
- 37-39
- ISSN
- 0376-4710
- CODEN
- IJCAD
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 18001214
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; ELECTRIC CONDUCTIVITY; INFRARED SPECTRA; LIGANDS; NMR SPECTRA; STRUCTURAL CHEMICAL ANALYSIS; ZIRCONIUM CHLORIDES; ZIRCONIUM COMPLEXES
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; ELECTRICAL PROPERTIES; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Notes
- 10 refs.