Intrinsic profiles and the structure of liquid surfaces

We present a brief review of the advances made in the characterization of liquid surfaces over the last decade. We focus particularly on the links between the capillary wave theory, the density functional formalism and the direct evaluation of the intrinsic density profiles from computer simulations. A new perspective of the liquid surfaces is appearing, with a sharper view of their molecular structure, which opens new challenges for theoretical and experimental studies. Novel results on the intrinsic interfacial structure of molten salt liquid-vapor interfaces are presented. (paper)