Published 1997 | Version v1
Journal article

Crystal and molecular structure of new fullerides (Ph4P)2C60Hal (Hal = Br, I) and (Ph4As)2C60Cl

  • 1. RAN, Inst. Khimicheskoj Fiziki, Chernogolovka (Russian Federation)

Description

New stable on air fullerides (Ph4P)2C60Hal (Hal = Br, I) and (Ph4As)2C60Cl were synthesized and their crystal structure were determined. On the basis of their relative crystallochemical analysis fullerides obtained were shown to be isostructural. They are described by general formula (Ph4X)2C60Hal (X = H, As; Hal = Cl, Br, I) and crystallized in triclinic system. Anions C60- and Hal- occupy the centre-symmetrical positions, cations (PH4P)+ and (Ph4As)+ occupy the general positions. The main parameters of molecular structure are presented

Additional details

Additional titles

Original title (Russian)
Кристаллическая и молекулярная структура новых фуллеридов (Пх

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.11
Journal Page Range
p. 1982-1986.
ISSN
1026-3500
CODEN
IASKEA

Optional Information

Notes
14 refs.; 3 figs.