Published November 2005
| Version v1
Journal article
Study on charge transfer interaction and valence state of layered perovskite-type mixed valence complex [NH3(CH2)nNH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7, 8), by means of 197Au Moessbauer spectroscopy
- 1. University of Tokyo, Graduate School of Arts and Sciences (Japan)
- 2. Kyoto University Research Reactor Institute (Japan)
Description
Cs2[AuIX2][AuIIIX4](X = Cl, Br, and I) is well known for the three-dimensional perovskite-type gold mixed valence system. Recently, layered perovskite-type gold mixed valence complexes, [NH3(CH2)nNH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7 and 8), have been synthesized. We have investigated the relationship between the structural dimensionality and the AuI-AuIII charge transfer interaction for Cs2[AuII2][AuIIII4] and [NH3(CH2)nNH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7 and 8) by means of 197Au Moessbauer spectroscopy.
Additional details
Identifiers
Publishing Information
- Journal Title
- Hyperfine Interactions
- Journal Volume
- 166
- Journal Issue
- 1-4
- Journal Page Range
- p. 403-407
- ISSN
- 0304-3843
- CODEN
- HYINDN
Conference
- Title
- 28. international conference on the applications of the Moessbauer effect
- Acronym
- ICAME 2005
- Dates
- 4-9 Sep 2005
- Place
- Montpellier (France)
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43029910
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- AMMONIA; CARBON SULFIDES; CESIUM SULFIDES; COMPLEXES; GOLD 197; GOLD COMPLEXES; INTERACTIONS; MOESSBAUER EFFECT; PEROVSKITE; THREE-DIMENSIONAL CALCULATIONS; VALENCE
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CESIUM COMPOUNDS; CHALCOGENIDES; COMPLEXES; GOLD ISOTOPES; HEAVY NUCLEI; HYDRIDES; HYDROGEN COMPOUNDS; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MINERALS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NUCLEI; ODD-EVEN NUCLEI; OXIDE MINERALS; PEROVSKITES; RADIOISOTOPES; SECONDS LIVING RADIOISOTOPES; STABLE ISOTOPES; SULFIDES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 2006 Springer Science+Business Media, Inc.