Published September 1994 | Version v1
Journal article Metadata-only

Preparation and crystal structures of hexanitroruthenates(2) of lithium and potassium

Creators

Description

A method of preparation has been described and crystal structure has been studied of Li4[Ru(NO2)6] · 12H2O (1) and K4[Ru(NO2)6] (2). Crystallographic data for 1 are as follows: a=11.749(9), c=16.807(12) A, sp.gr. I4, Z=4, dcalcld=1.778 g/cm3; for 2: a=8.595(1) A, α=52.23(2) deg; sp.gr. R3, Z=1, dcalcld.=2.414 g/cm3. The structures are built from complex anions [Ru(NO2)6]4- and alkali metal cations. Coordination polyhedrons of Ru are nearly regular octahedrons formed by nitrogen atoms of nitrite groups with Ru-N bond length of 2.054-2.102 A. 8 refs.; 4 figs.; 4 tabs

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллические структуры гексанитрорутенатов(2) лития и калия

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
35
Journal Issue
5
Journal Page Range
p. 171-177.
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27055366
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND LENGTHS; CHEMICAL PREPARATION; CRYSTAL LATTICES; DENSITY; HYDRATES; LATTICE PARAMETERS; LITHIUM COMPOUNDS; MOLECULAR STRUCTURE; NITRITES; POTASSIUM COMPOUNDS; RUTHENIUM COMPLEXES; SPACE GROUPS
Descriptors DEC
ALKALI METAL COMPOUNDS; COMPLEXES; CRYSTAL STRUCTURE; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES