Published March 15, 1983
| Version v1
Journal article
A tetrahedral CdS2O2 stereochemistry: the structure of (dinitrato-O)bis(1,1,3,3,-tetramethyl-2-thiourea-S)cadmium(II), Cd(C5H12N2S)2(NO3)2, and its 113Cd NMR spectra
- 1. South Carolina Univ., Columbia (USA). Dept. of Chemistry
Description
The structure of the title compound consists of isolated ion triplets from an approximately tetrahedral environment about Cd with Cd-S distances of 2.498(2) A and Cd-O distances of 2.295(4) A. These species are separated from their neighbors by ordinary van der Waals distances. The solid-state magic-angle spinning 113Cd NMR of this compound was observed at +263 p.p.m., deshielded from the aqueous Cd(ClO4)2 standard. (Auth.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. C
- Journal Volume
- 39
- Journal Issue
- 3
- Series
- Acta Crystallogr., Sect. C.
- Journal Page Range
- 331-333
- ISSN
- 0108-2701
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 14765644
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CADMIUM COMPOUNDS; CADMIUM 113; CHEMICAL SHIFT; LIGANDS; MONOCLINIC LATTICES; NUCLEAR MAGNETIC RESONANCE; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; STEREOCHEMISTRY; X-RAY DIFFRACTION
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CADMIUM ISOTOPES; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; EVEN-ODD NUCLEI; INTERMEDIATE MASS NUCLEI; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MAGNETIC RESONANCE; NUCLEI; ORGANIC COMPOUNDS; RADIOISOTOPES; RESONANCE; SCATTERING; STABLE ISOTOPES; YEARS LIVING RADIOISOTOPES