Published July 1981
| Version v1
Journal article
Radiolysis of polycrystals of platinum (2) tetraamminocomplexes
- 1. Moskovskij Gosudarstvennyj Univ. (USSR)
Description
The behaviour of tetraammine complexes of platinum (2) (chloride, bromide and iodide) under the effect of γ-irradiation is studied. In the limits of the absorbed doses of 100-2000 Mrad the dose rate is 2 Mrad/h, the compounds investigated decompose with the separation of ammonia, platinum and halogens passing the stage of trans-tetraammine formation. At that, no oxidation of the initial compound of divalent platinum with radiolysis products is observed. The radiation-chemical stability of the compounds decreases in the series: chloride>bromide>iodide
Additional details
Additional titles
- Original title (Russian)
- Радиолиз поликристаллов тетраамминокомплексов платины (2)
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Khim.
- Journal Issue
- no.7
- Series
- Izv. Akad. Nauk SSSR, Ser. Khim.
- ISSN
- 0002-3353
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 13650001
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AMMONIA; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; COBALT 60; DOSE RATES; HALIDES; PLATINUM COMPLEXES; POLYCRYSTALS; RADIATION DOSES; RADIOLYSIS; STABILITY
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COBALT ISOTOPES; COMPLEXES; CRYSTALS; DECOMPOSITION; HALOGEN COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; KINETICS; MINUTES LIVING RADIOISOTOPES; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NUCLEI; ODD-ODD NUCLEI; RADIATION EFFECTS; RADIOISOTOPES; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES; YEARS LIVING RADIOISOTOPES
Optional Information
- Notes
- For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).