Published October 1980
| Version v1
Journal article
N-chloralkyl-nitridochloro complexes of molybdenum(V) and rhenium(VI)
Description
The complex AsPh4[Cl4MoN-C2Cl5] (I) is formed by the reduction of AsPh4[Cl5MoN-C2Cl5] with acetonitrile, whereas the rhenium complexes AsPh4[Cl5ReN-R] (R = CCl3, C2Cl5) (II, III) can be obtained by the reaction of tetraphenylarsonium chloride with the corresponding POCl3 solvates Cl3PO-(Cl4)ReN-R. According to the i.r. spectra the complex anions of I-III contain metal nitrogen triple bonds, in which the d1 system causes a Jahn-Teller stabilization of the MN bond. (author)
Additional details
Additional titles
- Original title (German)
- N-chloralkylierte Nitridochlorokomplexe von Molybdaen(V) und Rhenium(VI)
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 469
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 45-50
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 12594853
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL BONDS; CHEMICAL PREPARATION; ETHANE; INFRARED SPECTRA; JAHN-TELLER EFFECT; MOLYBDENUM COMPLEXES; ORGANIC CHLORINE COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RHENIUM COMPLEXES
- Descriptors DEC
- ALKANES; COMPLEXES; HYDROCARBONS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES