Published 1983
| Version v1
Journal article
Configuration mixing in the groundstate of Ce
Description
4f electrons at the beginning of the rare earth series are weakly bound yet highly localized. Their virtual excitations create core change fluctuations which strongly enhance excitonic effects. The dynamic interaction lead to a new groundstate which may viewed as a boundstate of a 4f electron and an f-exciton. The 4f-hole Greens' function is also strongly modified and shows two poles instead of one pole in the one-electron picture. The photoemission experiments and the X-ray edge absorption experiments in cerium and its metallic compounds are explained in this model. The new groundstate also provides a basis for the understanding of the γ-α phase transition of cerium. (Auth.)
Additional details
Publishing Information
- Journal Title
- Helv. Phys. Acta
- Journal Volume
- 56
- Journal Issue
- 1-3
- Series
- Helv. Phys. Acta.
- Journal Page Range
- 147-161
- ISSN
- 0018-0238
Conference
- Title
- 3. General conference of the Condensed Matter Division of the European Physical Society.
- Dates
- 28-30 Mar 1983.
- Place
- Lausanne (Switzerland).
INIS
- Country of Publication
- Switzerland
- Country of Input or Organization
- Switzerland
- INIS RN
- 15000156
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- BINDING ENERGY; CERIUM; CONFIGURATION MIXING; ELECTRONIC STRUCTURE; FERMI LEVEL; GREEN FUNCTION; GROUND STATES; HAMILTONIANS; HARTREE-FOCK METHOD; PHASE TRANSFORMATIONS; PHOTOEMISSION; WAVE FUNCTIONS
- Descriptors DEC
- ELEMENTS; EMISSION; ENERGY; ENERGY LEVELS; FUNCTIONS; INTERACTIONS; MATHEMATICAL OPERATORS; METALS; QUANTUM OPERATORS; RARE EARTHS; SECONDARY EMISSION