Published 1983 | Version v1
Journal article

Configuration mixing in the groundstate of Ce

  • 1. Bell Labs., Murray Hill, NJ (USA)

Description

4f electrons at the beginning of the rare earth series are weakly bound yet highly localized. Their virtual excitations create core change fluctuations which strongly enhance excitonic effects. The dynamic interaction lead to a new groundstate which may viewed as a boundstate of a 4f electron and an f-exciton. The 4f-hole Greens' function is also strongly modified and shows two poles instead of one pole in the one-electron picture. The photoemission experiments and the X-ray edge absorption experiments in cerium and its metallic compounds are explained in this model. The new groundstate also provides a basis for the understanding of the γ-α phase transition of cerium. (Auth.)

Additional details

Publishing Information

Journal Title
Helv. Phys. Acta
Journal Volume
56
Journal Issue
1-3
Series
Helv. Phys. Acta.
Journal Page Range
147-161
ISSN
0018-0238

Conference

Title
3. General conference of the Condensed Matter Division of the European Physical Society.
Dates
28-30 Mar 1983.
Place
Lausanne (Switzerland).

INIS

Country of Publication
Switzerland
Country of Input or Organization
Switzerland
INIS RN
15000156
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BINDING ENERGY; CERIUM; CONFIGURATION MIXING; ELECTRONIC STRUCTURE; FERMI LEVEL; GREEN FUNCTION; GROUND STATES; HAMILTONIANS; HARTREE-FOCK METHOD; PHASE TRANSFORMATIONS; PHOTOEMISSION; WAVE FUNCTIONS
Descriptors DEC
ELEMENTS; EMISSION; ENERGY; ENERGY LEVELS; FUNCTIONS; INTERACTIONS; MATHEMATICAL OPERATORS; METALS; QUANTUM OPERATORS; RARE EARTHS; SECONDARY EMISSION