Published March 2007 | Version v1
Journal article

Nuclear magnetic resonance of 57Fe in Al-, Ga- and Ti-substituted magnetite above Verwey temperature

  • 1. Faculty of Mathematics and Physics, Charles University, V Holesovickach 2, 180 00 Prague 8 (Czech Republic)
  • 2. Department of Physics, Eindhoven University of Technology, POB 512, NL-5600 MB Eindhoven (Netherlands)

Description

Magnetite single crystals with Al, Ga and Ti substitutions were measured by means of 57Fe nuclear magnetic resonance (NMR) technique. Satellite structure of NMR spectra well above the Verwey temperature was detected and analyzed to obtain information on the distribution of substituting cations on iron sublattices. It was confirmed that Al and Ti enter iron octahedral B-sites. Ga strongly prefers tetrahedral A-sites, nevertheless a low presence of Ga cations in B-sites was detected

Additional details

Identifiers

DOI
10.1016/j.jmmm.2006.10.867;
PII
S0304-8853(06)02103-2;

Publishing Information

Journal Title
Journal of Magnetism and Magnetic Materials
Journal Volume
310
Journal Issue
2
Journal Page Range
p. 2555-2557
ISSN
0304-8853
CODEN
JMMMDC

Conference

Title
17. international conference on magnetism
Dates
20-25 Aug 2006
Place
Kyoto (Japan)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
39026950
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ALUMINIUM COMPOUNDS; CATIONS; GALLIUM COMPOUNDS; MAGNETITE; MONOCRYSTALS; NMR SPECTRA; NUCLEAR MAGNETIC RESONANCE; SPIN ECHO; TITANIUM COMPOUNDS
Descriptors DEC
CHARGED PARTICLES; CRYSTALS; IONS; IRON ORES; MAGNETIC RESONANCE; MINERALS; ORES; OXIDE MINERALS; RESONANCE; SPECTRA; TRANSITION ELEMENT COMPOUNDS

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.