Published November 10, 1987
| Version v1
Journal article
Synthesis of 4-methyl-8-oxo-4e-nonenal by the oxidative cleavage of e-geranylacetone. A 13C NMR spectral study of the intermediates
- 1. Ukrainian Printing Industry Research Institute, Lvov (USSR)
Description
The oxidative cleavage of E-geranylacetone for the preparation of 4-methyl-8-oxo-4E-nonenal was improved. A 13C NMR spectral study of the intermediates, 9-bromo-6,10-dimethyl-10-hydroxy-5E-undecen-2-one, 6,10-dimethyl-9,10-epoxy-5E-undecen-2-one, and 6,10-dimethyl-9,10-dihydroxy-5E-undecen-2-one and a side-product, 2,2,5,5-tetramethyl-4-(3-methyl-7-oxo-3E-octenyl)-1,3-dioxolane showed the predominant conformations of these compounds in the solvents studied
Additional details
Publishing Information
- Journal Title
- J. Org. Chem. USSR (Engl. Transl.)
- Journal Volume
- 23
- Journal Issue
- 6
- Series
- J. Org. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 1093-1197
- ISSN
- 0022-3271
- CODEN
- JOCYA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19087110
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ACETONE; ALDEHYDES; CARBON 13; CHEMICAL SHIFT; COUPLING CONSTANTS; EPOXIDES; HEAVY WATER; HYDROXY COMPOUNDS; INFRARED SPECTRA; ISOMERIZATION; J-J COUPLING; KETONES; MULTIPLETS; NMR SPECTRA; OXIDATION; REACTION INTERMEDIATES; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- CARBON ISOTOPES; CHEMICAL REACTIONS; COUPLING; EVEN-ODD NUCLEI; HYDROGEN COMPOUNDS; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; POLAR SOLVENTS; SOLVENTS; SPECTRA; STABLE ISOTOPES; WATER
Optional Information
- Notes
- Translated from Zh. Org. Khim.; 23: No. 6, 1209-1215(Jun 1987).