Published 1987 | Version v1
Journal article

Acidic monophosphates of rare earths

  • 1. Moskovskij Gosudarstvennyj Univ. (USSR)

Description

Acidic monophosphates of rare earths La4H3(PO4)5(1), Ln2H3(PO4)3x1.5H2O (Ln=Nd, Pr)(2), Ln(H2PO4)3, (Ln=Sm-Gd)(3), LnH3(PO4)2xH2O (Ln=Dy-Lu)(4) and products of their dehydration are studied by DTA, X-ray diffraction, 1H NMR and polarography methods. Lattice parameters are given; syngony 1 is monoclinic, 2, 3-hexagonal, 4-rhombic. Structure interactions with LnPO4xnH2O hydrates, character of proton-containing groupings are detected; diagrams of thermal decomposition are given

Additional details

Additional titles

Original title (Russian)
Кислые монофосфаты редкоземельных элементов

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
13
Journal Issue
1
Series
Koord. Khim.
Journal Page Range
56-62
ISSN
0132-344X
CODEN
KOKHD

Optional Information

Notes
For English translation see the journal Soviet Journal of Coordination Chemistry (USA).