Published 2001 | Version v1
Book Metadata-only

A comparative study of edta-gel derived BSCCO and Pb-BSCCO systems by thermoanalytical (TG/DTA) and x-ray diffraction (XRD) techniques

Creators

  • 1. Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Applied Physics Div.
  • 2. Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan)
  • 3. University of Manchester (United Kingdom). Manchester Materials Science Center
  • 4. Quaid-e-Azam Univ., Islamabad (Pakistan). Dept. of Chemistry
  • 5. University of Peshawar (Pakistan). Chemistry Dept.
  • 6. Allama Iqbal Open Univ., Islamabad (Pakistan). Dept. of Chemistry

Description

Superconducting phases in the BSCCO and Pb-BSCCO systems have been produced by ethylenediaminetetraacetic acid (EDTA) gel-derived route using nitrates of metal salts. Thermal decomposition and formation of various phases of gel and calcined powder of both BSCCO and Pb-BSCCO have been investigated by thermoanalytical and XRD techniques. It has been observed that Pb-containing system shows large volume of high T/sub c/ phase as compared to Pb-free system at the same sintering temperature. Thermal behavior (TG) indicates that sample doped with Pb decomposed in a series of steps while Pb-free sample, in a single step. The effect of Pb is shown to lower the sintering temperature (845 degree C) of formation of high T/sub c/ phase (2223). However, in the Pb-free sample the high T/sub c/ phase produced at higher temperature (860 degree C). (author)

Part of:
Advanced materials 2001

Additional details

Publishing Information

Publisher
Doctor A.Q. Khan Research Labs., Islamabad Pakistan
Imprint Place
Islamabad (Pakistan)
Imprint Title
Advanced materials 2001
Imprint Pagination
520 p.
Journal Page Range
p. 255-260

Conference

Title
7. International Symposium on Advanced Materials
Dates
17-21 Sep 2001
Place
Islamabad (Pakistan)

INIS

Country of Publication
Pakistan
Country of Input or Organization
Pakistan
INIS RN
34064965
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BARIUM OXIDES; COPPER OXIDES; CRITICAL TEMPERATURE; DIFFERENTIAL THERMAL ANALYSIS; DOPED MATERIALS; EDTA; HIGH-TC SUPERCONDUCTORS; LEAD OXIDES; SINTERING; SOL-GEL PROCESS; SUPERCONDUCTIVITY; THERMAL GRAVIMETRIC ANALYSIS; THERMOCHEMICAL DIAGRAMS; X-RAY DIFFRACTION
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; AMINO ACIDS; BARIUM COMPOUNDS; CARBOXYLIC ACIDS; CHALCOGENIDES; CHELATING AGENTS; CHEMICAL ANALYSIS; COHERENT SCATTERING; COPPER COMPOUNDS; DIAGRAMS; DIFFRACTION; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; FABRICATION; GRAVIMETRIC ANALYSIS; INFORMATION; LEAD COMPOUNDS; MATERIALS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SUPERCONDUCTORS; THERMAL ANALYSIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION TEMPERATURE; TYPE-II SUPERCONDUCTORS

Optional Information