Published 1990 | Version v1
Journal article Metadata-only

Synthesis and structure of the first trinuclear cluster rhenium chalcohalide

Creators

  • 1. AN SSSR, Moscow (USSR). Inst. Ehlementoorganicheskikh Soedinenij
  • 2. AN Ukrainskoj SSR, Kiev (Ukrainian SSR). Inst. Obshchej i Neorganicheskoj Khimii

Description

A new rhenium thiochloride of Re3S7Cl7 composition is synthesized at 200 deg C temperature by ReOCl4 interaction with sulfur in S2Cl2 solution. An x-ray diffraction investigation has shown that the compound crystals are trigonal (a=8.999(3), c=22.516(5) A, sp. gr. P3, Z=4). Rhenium thiochloride is trinuclear cluster, constructed of [Re3(μ-S2)3(μ-S)Cl6]+ and Cl- ions, in which six sulfur atoms produce disulfide bridges perpendicular to Re-Re bonds, and the seventh sulfur atom and Cl-anion are located respectively above and under the plane of trigonal Re3 metal frame

Additional details

Additional titles

Original title (Russian)
Синтез и структура первого трехьядерного кластерного халкогалогенида рения

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
16
Journal Issue
8
Series
Koord. Khim.
Journal Page Range
1062-1066
ISSN
0132-344X
CODEN
KOKHD

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22041611
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHLORIDES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; RHENIUM COMPLEXES; SPACE GROUPS; SULFIDES; TRIGONAL LATTICES
Descriptors DEC
CHALCOGENIDES; CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; HALIDES; HALOGEN COMPOUNDS; SULFUR COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES