Published July 1987
| Version v1
Journal article
Rotational isomers of the radical-anions of 2-carbonyl-containing derivatives of 5-nitrofuran
- 1. Institute of Organic Synthesis, Riga, USSR
Description
The radical-anions of 2-carbonyl-containing derivatives of 5-nitrofuran were obtained by electrochemical generation. Their ESR spectra indicate the existence of a mixture of O,O-cis and O,O-trans rotational isomers. The parameters of the isomers were identified by INDO calculations. The more polar form (the cis isomer) is more stable in polar media
Additional details
Publishing Information
- Journal Title
- Chem. Heterocycl. Compd. (Engl. Transl.)
- Journal Volume
- 23
- Journal Issue
- 1
- Series
- Chem. Heterocycl. Compd. (Engl. Transl.).
- Journal Page Range
- 8-15
- ISSN
- 0069-3154
- CODEN
- CHCCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19021484
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ANIONS; ATOMIC MODELS; COMPUTERIZED SIMULATION; DIPOLE MOMENTS; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; ELECTRONIC STRUCTURE; FURANS; HYPERFINE STRUCTURE; ISOMERIZATION; ISOMERS; NITRO COMPOUNDS; ORGANIC SOLVENTS; QUANTUM MECHANICS; SPIN
- Descriptors DEC
- ANGULAR MOMENTUM; CHARGED PARTICLES; CHEMICAL REACTIONS; HETEROCYCLIC COMPOUNDS; IONS; MAGNETIC RESONANCE; MATHEMATICAL MODELS; MECHANICS; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PARTICLE PROPERTIES; RESONANCE; SIMULATION; SOLVENTS
Optional Information
- Notes
- Translated from Khim. Geterotsikl. Soedin.; 23: No. 1, 14-21(Jan 1987).