Published September 1977
| Version v1
Journal article
Synthesis and characterization of the difluorotris (fluorosulfate of uranium (V): UF2(SO3F)3
Creators
- 1. Centre d'Etudes Nucleaires de Saclay, Gif-sur-Yvette, France
Description
A new U(V) compound, UF2(SO3F)3, has been synthesized by the reaction of UF6 and SO3 in both the gaseous phase and CFCl3 solution. This leads to a blue-green solid, the x-ray powder diffraction pattern of which has been recorded. Its oxidation state has been deduced from chemical analysis, the electronic absorption spectrum, and magnetic measurements. The environment around uranium is discussed from Raman and infrared spectra recorded at ambient and liquid nitrogen temperatures
Additional details
Identifiers
- DOI
- 10.1021/ic50175a020;
Publishing Information
- Journal Title
- Inorganic Chemistry
- Journal Volume
- 16
- Journal Issue
- 9
- Series
- Inorg. Chem.
- Journal Page Range
- 2252-2257
- ISSN
- 0020-1669
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 9365033
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CHEMICAL REACTIONS; INFRARED SPECTRA; RAMAN EFFECT; SULFUR OXIDES; URANIUM COMPLEXES; URANIUM FLUORIDES
- Descriptors DEC
- ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; CHALCOGENIDES; COMPLEXES; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SPECTRA; SULFUR COMPOUNDS; SYNTHESIS; URANIUM COMPOUNDS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent