Published August 2008 | Version v1
Miscellaneous

In-situ monitoring of the valence changes of uranium (III) and some lanthanide Ions in a LiCl-KCl eutectic melt using the UV-VIS spectroscopic

  • 1. Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

Description

In this study, we have measured the absorption spectra of U(III), and europium, samarium and ytterbium ions on a real time basis. The UV spectra of the Eu, Sm, Yb ions showed direct evidence of a spontaneous valence reduction to di-valent species. Absorption spectroscopic method was successful in monitor the reduction process in an in-situ manner. This implies that the in-situ absorption spectroscopic method may be applied to monitor the related pyrochemical processes by selecting suitable key ions and spectroscopic properties

Part of:
2008 International Pyroprocessing Research Conference

Additional details

Publishing Information

Publisher
Korea Atomic Energy Research Institute
Imprint Place
Daejeon (Korea, Republic of)
Imprint Title
2008 International Pyroprocessing Research Conference
Imprint Pagination
150 p.
Journal Page Range
p. 84-85

Conference

Title
International Pyroprocessing Research Conference
Dates
24-27 Aug 2008
Place
Jeju (Korea, Republic of)

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
40101536
Subject category
S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
ABSORPTION SPECTRA; EUTECTICS; LITHIUM CHLORIDES; MONITORING; RARE EARTHS; SPECTROSCOPY; URANIUM; VALENCE
Descriptors DEC
ACTINIDES; ALKALI METAL COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; LITHIUM COMPOUNDS; LITHIUM HALIDES; METALS; SPECTRA

Optional Information